Publications:

2019

Electrochemical Synthesis of Individual Core@Shell and Hollow Ag/Ag2S Nanoparticles
D. A. Robinson, H. S. White
Nano Lett. 201919, 8, 5612-5619

Enhancing Lithium Insertion with Electrostatic Nanoconfinement in a Lithography Patterned Precision Cell
S. X. Li, N. S. Kim, K. McKelvey, C. Liu, H. S. White, G. W. Rubloff, S. B. Lee, M. A. Reed
ACS Nano.  2019. 13, 7, 8481-8489

Nanoscale Fluid Vortices and Nonlinear Electroosmotic Flow Drive Ion Current Rectification in the Presence of Concentration Gradients
J. Rabinowitz, M. A. Edwards, E. Whittier, K. Jayant, K. L. Shepard
J. Phys. Chem. A.2019.DOI: 10.1021/acs.jpca.9b04075

A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms
C. Sandford, M. A. Edwards, K. J. Klunder, D. P. Hickey, M. Li, K. Barman, M. S. Sigman, H. S. White and S. D. Minteer
Chem. Sci., 2019, 10, 6404-6422.

Observing Transient Bipolar Electrochemical Coupling on Single Nanoparticles Translocating through a Nanopore
C. Han, R. Hao, Y. Fan, M. A. Edwards, H. Gao, and B. Zhang
Langmuir, 201935, 22, 7180-7190

Electrochemically Driven, Ni-Catalyzed Aryl Amination: Scope, Mechanism, and Applications
Y. Kawamata, J. C. Vantourout, D. P. Hickey, P. Bai, L. Chen, Q. Hou, W. Qiao, K. Barman, M. A. Edwards, A. F. Garrido-Castro, J. N. deGruyter, H. Nakamura, K. W. Knouse, C. Qin, K. J. Clay, D. Bao, C. Li, J. T. Starr, C. Garcia-Irizarry, N. Sach, H. S. White, M. Neurock, S. D. Minteer, and P. S. Baran
J. Am. Chem. Soc., 2019, 141 (15), pp 6392–6402

Voltammetric Determination of the Stochastic Formation Rate and Geometry of Individual H2,N2, and O2 Bubble Nuclei
M. A. Edwards, H. S. White, H. Ren
ACS Nano, Article ASAP. DOI: 10.1021/acsnano.9b01015

2018 

 γ-Hemolysin Nanopore Is Sensitive to Guanine-to-Inosine Substitutions in Double-Stranded DNA at the Single-Molecule Level
Cherie S. Tan, Aaron M. Fleming , Hang Ren , Cynthia J. Burrows, and Henry S. White
J. Am. Chem. Soc., 2018, 140, 43, 14224-14234

Nanoscale Electrochemical Kinetics & Dynamics: The Challenges and Opportunities of Single-Entity Measurements
M. A. Edwards, D. A. Robinson, H. Ren, C. G. Cheyne, C. S. Tan, and H. S. White 
Faraday Discuss., 2018, 210, 9-28.

Effects of Instrumental Filters on Electrochemical Measurement of Single‐Nanoparticle Collision Dynamics
D. A. Robinson, M. A. Edwards, H. Ren, and H. S. White
ChemElectroChem, 2018, 5 (20), 3059-3067

The Nucleation Rate of Single O2 Nanobubbles at Pt Electrodes
Á. M. Soto, S. R. German, H. Ren, D. Meer, D. Lohse, M. A. Edwards, and H. S. White
Langmuir, 2018, 34 (25), pp 7309–7318

Single-Molecule Titration in a Protein Nanoreactor Reveals the Protonation/Deprotonation Mechanism of a C:C Mismatch in DNA
H. Ren, C. G. Cheyne, A. M. Fleming, C. J. Burrows, and H. S. White
J. Am. Chem. Soc., 2018, 140155153-5160

Nanopore Analysis of the 5‑Guanidinohydantoin to Iminoallantoin Isomerization in Duplex DNA
T. Zeng, A. M. Fleming, Y. Ding, H. Ren, H. S. White, C. J. Burrows
J. Org. Chem., 2018, 83 (7), pp 3973–3978

Nanopore Opening at Flat and Nanotip Conical Electrodes during Vesicle Impact Electrochemcial Cytometry
X. Li, Lin Ren, J. Dunevall, D. Ye, H. S. White, M. A. Edwards, and A. G. Ewing
ACS Nano, 2018, 12 (3), pp 3010–3019

Single Ag Nanoparticle Collisions within a Dual-Electrode Micro-Gap Cell
K. McKelvey, D. A. Robinson, N. J. Vitti, M. A. Edwards, H. S. White
Faraday Discuss., 2018, 210, 189-200

Critical Nuclei Size, Rate, and Activation Energy of H2 Gas Nucleation
S. R. German, M. A. Edwards, H.Ren, H. S. White
J. Am. Chem. Soc., 2018, 140 (11), pp 4047–4053

Exploring the suitability of different electrode materials for hypochlorite quantification at high concentration in alkaline solutions
R. E.P. Meyler, M. A. Edwards, J. V. Macpherson 
Electrochemistry Communications, 2018, 86 21-25.

 

2017 

Selective increase in CO2 electroreduction activity at grain-boundary surface terminations                                 R. G. Mariano, K. McKelvey, H. S. White, M. W. Kanan
Science, 2017, 358 1187-1192.

Collision Dynamics During the Electrooxidation of Individual Silver Nanoparticles
D. A Robinson, Y. Liu, M. A. Edwards, N. J. Vitti, S. M. Oja, B. Zhang, H. S. White
J. Am. Chem. Soc., 2017,139 (46), pp 16923–16931.

Redox Cycling in Nanogap Electrochemical Cells
H. S. White, K. McKelvey
Current Opinion in Electrochemistry, 2017, 7:48–53.

Three-Dimensional Super-resolution Imaging of Single Nanoparticles Delivered by Pipettes
Y. Yu, V. Sundaresan, S. Bandyopadhyay, Y. Zhang, M. A. Edwards, K. McKelvey, H. S. White, K. A. Willets.
ACS Nano2017, 11 (10), pp 10529–10538.

Collision and Oxidation of Silver Nanoparticles on a Gold Nanoband Electrode
F. Zhang, M. Edwards, R. Hao, H. S. White, B. Zhang
J. Phys. Chem. C, 2017121 (42), pp 23564–23573.

Microscale 2.5D Batteries
K. McKelvey, A. A. Talin, B. Dunn, and H. S. White
Journal of the Electrochemical Society, 2017, 164(12), A2500-A2503.

Nanopipettes as a Tool for Single Nanoparticle Electrochemistry
K. McKelvey, S. R. German, Y. Zhang, H. S. White, and M. A. Edwards
Current Opinion in Electrochemistry, 2017, 6:4–9.

Electrochemical Generation of Individual O2 Nanobubbles via H2O2 Oxidation
H. Ren, S. R. German, M. A. Edwards, Q. Chen, and H. S. White
J. Phys. Chem. Lett., 2017, 8, 2450-2454.

Interrogation of Base Pairing of the Spiroiminodihydantoin Diastereomers Using the α-Hemolysin Latch
T. Zeng, A. M. Fleming, Y. Ding, H. S. White, and C. J. Burrows
Biochemistry, 2017, 56 (11), 1596–1603.

Dynamics of a DNA Mismatch Site Held in Confinement Discriminate Epigenetic Modifications of Cytosine
R. P. Johnson, A. M. Fleming, R. T. Perera, C. J. Burrows, and H. S. White
J. Am. Chem. Soc.,  2017, 139 (7), 2750–2756.

The dynamic steady state of an electrochemically generated nanobubble
Y. Liu, M. A. Edwards, S. R. German, Q. Chen, and H. S. White
Langmuir,  2017, 33 (8), 1845–1853.

Observation of Multipeak Collision Behavior during the Electro-Oxidation of Single Ag Nanoparticles
S. M Oja, D. A. Robinson, N. J. Vitti, M. A. Edwards, Y. Liu, H. S. White, and B. Zhang
J. Am. Chem. Soc.,  2017, 139 (2), 708–718.

Single Nanochannel Platform for Detecting Chiral Drugs
H. Li, I. Boussouar, Q. Chen, X. Chen, Y. Zhang, F. Zhang, D. Tian, and H. S. White
Anal. Chem.,  2017, 89 (2), 1110–1116.

2016

Allen J. Bard–A Pioneer in Electrochemistry for over 60 Years
S. D. Minteer, and H. White
J. Electrochem. Soc.,  2016, 163(4), Y13.

Kinetics of T3-DNA Ligase-Catalyzed Phosphodiester Bond Formation Measured Using the α-Hemolysin Nanopore

C. S. Tan, J. Riedl, A. M. Fleming, C. J. Burrows, and H. S. White
ACS Nano, 201610 (12), 11127–11135.

A Tribute to Christian Amatore
P. Hapiot, Z. Tian, and H. S. White
ChemElectroChem, 2016, 3 (12), 1965-1966.

Electrochemistry at the Nanoscale: Tackling Old Questions, Posing New Ones
S. Lemay and H. S. White
Acc. Chem. Res., 2016, 49 (11), 2371–2371.

Fabrication, Testing and Simulation of All Solid State Three Dimensional Li-ion Batteries
A. A. Talin, D. Ruzmetov, A. Kolmakov, K. McKelvey, N. Ware, F. El Gabaly, B. S. Dunn, and H. S. White
ACS Appl. Mater. Interfaces, 2016, 8 (47), 32385-32391.

Highlights from the Faraday Discussion on Single Entity Electrochemistry, York, UK, August–September 2016
P. Actis, C. L. Bentley, M. A. Edwards, and L. Jacobse 
Chem. Comm., 2016, 52, 13934-13940.

Voltage-Rectified Current and Fluid Flow in Conical Nanopores
W. Lan, M. A. Edwards, L. Luo, R. T. Perera, X. Wu, C. R. Martin, and H. S. White
Acc. Chem. Res., 2016, 49 (11), 2605–2613.

Laplace Pressure of Individual H2 Nanobubbles from Pressure-Addition Electrochemistry
S. R. German, M. A. Edwards, Q. Chen, and H. S. White
Nano Lett., 2016, 16 (10), 6691–6694.

Electrochemistry of single nanobubbles. Estimating the critical size of bubble-forming nuclei for gas-evolving electrode reactions
S. R. German, M. A. Edwards, Q. Chen, Y. Liu, L. Luo and H. S. White
Faraday Discuss., 2016, 193, 223-240.

Energetics of base flipping at a DNA mismatch site confined at the latch constriction of α-hemolysin
R. P. Johnson, R. T. Perera, A. M. Fleming, C. J. Burrows and H. S. White
Faraday Discuss., 2016, 193, 471-485.

Resistive Pulse Delivery of Single Nanoparticles to Electrochemical Interfaces
K. McKelvey, M. A. Edwards, and H. S. White
J. Phys. Chem. Lett., 2016, 7, 3920–3924.

Redox Cycling in Nanogap Electrochemical Cells. The Role of Electrostatics in Determining the Cell Response
Q. Chen, K. McKelvey, M. A. Edwards, and H. S. White
J. Phys. Chem. C, 2016, 120 (31), 17251–17260.

Nanoreactors: Small Spaces, Big Implications in Chemistry
S. H. Petrosko, R. Johnson, H. S. White, and C. A. Mirkin
J. Am. Chem. Soc., 2016, 138 (24), 7443–7445.

Multipass Resistive-Pulse Observations of the Rotational Tumbling of Individual Nanorods

Y. Zhang, M. A. Edwards, S. R. German, and H. S. White
J. Phys. Chem. C, 2016, 120 (37), 20781–20788.

Electrochemical Measurement of Hydrogen and Nitrogen Nanobubble Lifetimes at Pt Nanoelectrodes

S. R. German, Q. Chen, M. A. Edwards, and H. S. White
J. Electrochem. Soc., 163(4), H3160-H3166.

Base Flipping within the alpha-hemolysin Latch Allows Single-Molecule Identification of Mismatches in DNA
R. P. Johnson, A. M. Fleming, L. R. Beuth, C. J. Burrows, and H. S. White
J. Am. Chem. Soc., 2016, 138 (2), 594–603.

2015

A high-speed multipass coulter counter with ultra-high resolution
M. A. Edwards, S. R. German, J. E. Dick, A. J. Bard, and H. S. White
ACS Nano, 2015, 9 (12), 12274–12282.

Differentiation of G:C vs. A:T and G:C vs. G:mC base pairs in the latch zone of alpha-hemolysin
Y. Ding, A. M. Fleming, H. S. White, and C. J. Burrows
ACS Nano,2015, 9 (11), 11325–11332.

Effect of the electric double layer on the activation energy of ion transport in conical nanopores
R. T. Perera, R. P. Johnson, M. A. Edwards, and H. S. White
J. Phys. Chem. C., 2015119 (43), 24299–24306.

Electrochemical Nucleation of Stable N2 Nanobubbles at Pt Nanoelectrodes
Q. Chen, H. S. Wiedenroth, S. R. German, and H. S. White
J. Am. Chem. Soc., 2015, 137 (37), 12064–12069.

Ion Transport within High Electric Fields in Nanogap Electrochemical Cells                                                                J. Xiong, Q. Chen, M. A. Edwards, and H. S. White
ACS Nano, 2015, 9(8), 8520-8529.

Size-dependent electronic structure controls activity for ethanol electro-oxidation at Ptn/indium tin oxide (n = 1 to 14)                                                                                                                                                                                  A. Von Weber, E. T. Baxter, S. Proch, M. D. Kane, M. Rosenfelder, H. S. White, and S. L. Anderson
Phys. Chem. Chem. Phys., 2015, 17(27), 17601-17610.

Cluster size controls branching between water and hydrogen peroxide production in electrochemical oxygen reduction at Ptn/ITO                                                                                                                                                         A. Von Weber, E. T. Baxter, H. S. White, and S. L. Anderson
J. Phys. Chem. C, 2015, 119(20), 11160-11170.

Electrochemical generation of a hydrogen bubble at a recessed platinum nanopore electrode                              Q. Chen, L. Luo, and H. S. White
Langmuir, 2015, 31(15), 4573-4581.

Sizing Individual Au Nanoparticles in Solution with Sub-Nanometer Resolution
S. R. German, T. S. Hurd, H. S. White, and T. L. Mega
ACS Nano, 2015, 9(7), 7186-7194.

Nanopore Detection of 8-Oxoguanine in the Human Telomere Repeat Sequence
N. An, A. M. Fleming, H. S. White, and C. J. Burrows
ACS Nano, 2015, 9(4), 4296–4307

Detection of benzo [a] pyrene-guanine adducts in single-stranded DNA using the α-hemolysin nanopore
R. T. Perera, A. M. Fleming, R. P. Johnson, C. J. Burrows, and H. S. White
Nanotechnology, 2015, 26(7), 074002

Current Response for a Single Redox Moiety Trapped in a Closed Generator-Collector System: The Role of Capacitive Coupling
S. W. Feldberg and M. A. Edwards
Anal. Chem., 2015, 87(7), 3778-3783

2014

Temperature and electrolyte optimization of the a-hemolysin latch sensing zone for detection of base modification in double-stranded DNA
R. P. Johnson, A. M. Fleming, Q. Jin, C. J. Burrows, and H. S. White
Biophys. J. , 2014, 107(4), 924-931.

Negative Differential Electrolyte Resistance in a Solid-State Nanopore Resulting from Electroosmotic Flow Bistability
L. Lou, D. A. Holden, and H. S. White
ACS Nano. , 2014, 8(3), 3023-3030.

Effect of Surface Charge on the Resistive Pulse Waveshape during Particle Translocation through Glass Nanopores
W. Lan, C. Kubeil, J. Xiong, A. Bund, and H. S. White
J. Phys. Chem. C. , 2014, 118(5), 2726-2734.

Electron-Transfer Kinetics and Electric Double Layer Effects in Nanometer-Wide Thin-Layer Cells
L. Fan, Y. Liu, J. Xiong, H. S. White, and S. Chen
ACS Nano. , 2014, 8(10), 10426-10436.

Electrochemical Measurements of Single H2 Nanobubble Nucleation and Stability at Pt Nanoelectrodes
Q. Chen, L. Luo, H. Faraji, S. W. Feldberg, and H. S. White
J. Phys. Chem. Lett. , 2014, 5(20), 3539-3544.

Resistive-Pulse Analysis of Nanoparticles
L. Luo, S. R. German, W. Lan, D. A. Holden, T. L. Mega, and H. S. White
Ann. Rev. of Anal. Chem. , 2014, 7, 513-535.

Effect of an Electrolyte Cation on Detecting DNA Damage with the Latch Constriction of α-Hemolysin
R. P. Johnson, A. M. Fleming, C. J. Burrows, and H. S White
J. Phys. Chem. Lett., 2014, 5(21), 3781-3786.

2013

Base-Excision Repair Activity of Uracil-DNA Glycosylase Monitored Using the Latch Zone of α-Hemolysin
Q. Jin, A. M. Fleming, R. P. Johnson, Y. Ding, C. J. Burrows, and H. S. White
J. Am. Chem. Soc., 2013, 135(51), 19347-19353.

Nanomaterials in Analytical Chemistry
F. S. Ligler and H. S. White
Anal. Chem., 2013, 85(23), 11161-11162.

Structural Destabilization of DNA Duplexes Containing Single-Base Lesions Investigated by Nanopore Measurements
Q. Jin, A. M. Fleming, Y. Ding, C. J. Burrows, and H. S. White
Biochemistry, 2013, 52(45), 7870-7877.

Electrogeneration of Single Nanobubbles at Sub-50-nm-Radius Platinum Nanodisk Electrodes
L. Luo and H. S. White
Langmuir, 2013, 29(35), 11169-11175.

Electrical Current Signatures of DNA Base Modifications in Single Molecules Immobilized in the α-Hemolysin Ion Channel
A. H. Wolma, A. M. Fleming, N. An, L. He, H. S. White, and C. J. Burrows
Isr. J. Chem., 2013, 53(6-7), 417-430.

Strong Effects of Cluster Size and Air Exposure on Oxygen Reduction and Carbon Oxidation Electrocatalysis by Size-Selected Ptn (n ≤ 11) on Glassy Carbon Electrodes
S. Proch, M. Wirth, H. S. White, and S. L. Anderson
J. Am. Chem. Soc., 2013, 135(8), 3073-3086.

Controlling Nanoparticle Dynamics in Conical Nanopores
S. R. German, L. Luo, H. S. White, and T. L. Mega
J. Phys. Chem C, 2013, 117(1), 703-711.

The i–V response of an electrochemical cell comprising two polarizable microelectrodes and the influence of impurities on the cell response
J. Xiong and H. S. White
J. Electroanal. Chem., 2013, 688, 354-359.

2012

Modulation of the current signatures of DNA abasic site adducts in the α-hemolysin ion channel
N. An, H. S. White, and C. J. Burrows
Chem. Comm., 2012, 48, 11410-11412.

Tunable Negative Differential Electrolyte Resistance in a Conical Nanopore in Glass
L. Luo, D. A. Holden, W. Lan, and H. S. White
ACS Nano, 2012, 6(7), 6507-6514.

Crown ether–electrolyte interactions permit nanopore detection of individual DNA abasic sites in single molecules
N. An, A. M. Fleming, H. S. White, and C. J. Burrows
PNAS, 2012, 109(29), 11504-11509.

Unzipping Kinetics of Duplex DNA Containing Oxidized Lesions in an α-Hemolysin Nanopore
Q. Jin, A. M. Fleming, C. J. Burrows, and H. S. White
J. Am. Chem. Soc., 2012, 134(26), 11006-11011.

Resistive-Pulse Detection of Multilamellar Liposomes
D. A. Holden, J. J. Watkins, and H. S. White
Langmuir, 2012, 28(19), 7572-7577.

Diffusional Motion of a Particle Translocating through a Nanopore
W. Lan and H. S. White
ACS Nano., 2012, 6(2), 1757-1765.

A Computationally Efficient Treatment of Polarizable Electrochemical Cells Held at a Constant Potential
M. K. Peterson, R. Kumer, H. S. White, and G. A. Voth
J. Phys. Chem. C, 2012, 116(7), 4903-4912.

2011

Pressure-Driven Nanoparticle Transport across Glass Membranes Containing a Conical-Shaped Nanopore
W. Lan, D. A. Holden, and H. S. White
J. Phys. Chem. C, 2011, 115(38), 18445-18452.

Sequence-Specific Single-Molecule Analysis of 8-Oxo-7,8-dihydroguanine Lesions in DNA Based on Unzipping Kinetics of Complementary Probes in Ion Channel Recordings
A. E. P. Schibel, A. M. Fleming, Q. Jin, N. An, J. Liu, C. P. Blakemore, H. S. White, and C. J. Burrows
J. Am. Chem. Soc., 2011, 133(37), 14778-14784.

Electrical signature of the deformation and dehydration of microgels during translocation through nanopores
D. A. Holden, G. R. Hendrickson, W. Lan, L. A. Lyon and H. S. White
Soft Matter, 2011, 7, 8035-8040.

Pressure-Dependent Ion Current Rectification in Conical-Shaped Glass Nanopores
W. Jin, D. A. Holden, and H. S. White
J. Am. Chem. Soc., 2011, 133(34), 13300-13303.

Post-Self-Assembly Covalent Chemistry of Discrete Multicomponent Metallosupramolecular Hexagonal Prisms
M. Wang, W. Jin, Y. Zheng, T. R. Cook, H. S. White, and P. J. Stang
J. Am. Chem. Soc., 2011, 133(28), 10752-10755.

Fluorescence Microscopy of the Pressure-Dependent Structure of Lipid Bilayers Suspended across Conical Nanopores
A. E. P. Schibel, E. C. Heider, J. M. Harris, and H. S. White
J. Am. Chem. Soc., 2011, 133(20), 7810-7815.

Nanoparticle Transport in Conical-Shaped Nanopores
W. Lan, D. A. Holden, B. Zhang, and H. S. White
Anal. Chem., 2011, 83(10), 3840-3847.

Resistive Pulse Analysis of Microgel Deformation During Nanopore Translocation
D. A. Holden, G. Hendrickson, L. A. Lyon, and H. S. White
J. Phys. Chem. C, 2011, 115(7), 2999-3004.

Last Updated: 10/8/19