2015 Publications

 

Intrinsic Organic-based Synthetic/Artificial Antiferromagnets, J. S. Miller, Chem. Eur.-J.21, 0000-0000 (2015). DOI: DOI: 10.1002/chem.201406205

 

The Importance of the Cation-Anion Interactions for the Relative Orientational Preference of Long, Multicenter Bond; A Case Study on the π-[TCNB]22- (TCNB = Tetracyanobenzene) and π-[TCNP]22- (TCNP = Tetracyanopyrazine) Dimers, M. Capdevila-Cortada, J. S. Miller, J. J. Novoa, Chem. Eur. J. 21, 0000-0000 (2015). DOI:   Front Cover:

 

Linear (1-D) Chain Structure of [Ru2(O2CMe)4]+[CoPc(CN)2]- Determined via Synchrotron Powder Diffraction Data, K. H. Stone, P. W. Stephens, M. B. Wainer, R. A. Davidson, J. S. Miller, Inorg. Chim. Acta 454, 116-119 (2015). DOI: doi.org/10.1016/j.ica.2014.06.013

 

Synthesis of [CrIII(NCMe)6]3+ and [CrIII(NCMe)5F]2+, K. J. Nelson, J. S. Miller, Inorg. Synth. 37, 0000-0000 (2015).

 

Synthesis, Crystal Structure, and Characterization of 4,5-Diaza-9-[4,5-bis(methylthio)-1,3-dithiol-2-ylidene]-fluorene (L) Metal Complexes [(TPyA)MII(L)](SbF6)2 (MII = Mn, Fe, Co; TPyA = tris(2-pyridylmethyl)amine), T. Culpitt, L. C. Spencer, I. A. Guzei, A. Simonson, J. S. Miller, K. J. Nelson, Inorg. Chim. Acta 427, 162-167 (2015). DOI: http://dx.doi.org/10.1016/j.ica.2014.12.004

 

2014 Publications

 

Organic and molecule-based Magnets, J. S. Miller, Materials Today, 17, 224-235 (2014). DOI: 10.1016/j.mattod.2014.04.023

 

Structure and Properties of Nitrogen-Rich 1,4-Dicyanotetrazine, C4N6. A Comparative Study with Related Tetracyano Electron Acceptors, H.-L. Vo, J. L. Arthur, M. l. Capdevila-Cortada, S. H. Lapidus, P. W. Stephens J. J. Novoa, A. M. Arif, R. K. Nagi, M. H. Bartl, J. S. Miller, J. Org. Chem.79, 8189-8201 (2014). DOI: doi.org/10.1021/jo5014004

 

The origin of the room temperature stability of [TTF]·+···[TTF]·+ long, multicenter bonds found in functionalized π-[R-TTF]22+ dimers included in the cucurbit[8]uril cavity, M. Capdevila-Cortada, J. S. Miller, J. J. Novoa, Chem. Eur. J.20, 7784-7795 (2014). DOI: 10.1002/chem.201402256

 

 Pressure-driven High to Low Spin transition in the Bimetallic Quantum Magnet [Ru2(O2CMe)4]3[Cr(CN)6], K. R. O'Neal, Z. Liu, J. S. Miller, R. S. Fishman, J. L. Musfeldt, Phys. Rev B. 87, 104301/1-6 (2014). DOI: 10.1103/PhysRevB.90.104301

2013 Publications

 Pressure Induced Crossover Between a Ferromagnetic and a Canted Antiferromagnetic State for [Bis(pentamethyl-cyclopentadienyl)iron(III)]+-[Tetracyanoethylenide]-, [FeCp*2][TCNE], J. G. DaSilva, R. Clérac, J. S. Miller, Inorg. Chem.52, 11677-11683 (2013). DOI: http://pubs.acs.org/doi/abs/10.1021/ic4021959

 

Pressure Induced Transition from Spin Glass-Like Behavior to Metamagnet Exhibiting Weak Ferromagnetism Observed for Decamethylferrocenium Hexacyanobutadienide, [FeCp*2]+[HCBD]-, J. G. DaSilva, J. S. Miller, J. Chem. Soc. Dalton Trans. 42, 8334-8338 (2013). DOI: 10.1039/c3dt50628b

 

PressureDependent Enhanced Tc and Magnetic Behavior of the Metamagnetic and Ferromagnetic Polymorphs of [FeIIICp*2]•+[TCNQ]•- (Cp* = pentamethylcyclopentadienide; TCNQ = 7,7,8,8-tetracyano-p-quinodimethane), J. G. DaSilva, J. S. Miller,Inorg. Chem. 52, 1108–1112 (2013).  DOI: org/10.1021/ic302420s

 

Pressure Dependent Magnetic Behavior of 1-D Ferrimagnetic meso-Tetrakis(4-chlorophenyl)porphyrinato)-manganese(III)Tetracyanoethenide, [MnIIITClPP]+[TCNE]•-, J. G. DaSilva, J. S. Miller, Polyhed. 68, 76-79 (2013). DOI:  http://dx.doi.org/10.1016/j.poly.2013.09.031

 

 Carrier Transport in V[TCNE]x (TCNE = tetracyanoethylene; x ~ 2) Organic-based Magnet, K. Pokhodnya, M. Bonner, V. Prigodin, A. J. Epstein, J. S. Miller, J. Phys.: Condens. Matter25, 196001/1-7 (2013).  DOI: 10.1088/0953-8984/25/19/196001

 

Pressure Induced Increase in Tc for the Organic-based Magnet FeII(TCNE)2 (TCNE = Tetracyanoethylene),V. Ksenofontov, P. Gütlich, J. S. Miller, Polyhed. 66, 56-59 (2013).  http://dx.doi.org/10.1016/j.poly.2013.02.012

 

Pressure Dependent Reversible Increase in Tc for the 2-D MnII(TCNE)I(OH2) and 3-D MnII(TCNE)3/2(I3)1/2•zTHF Organic-based Magnets, J. G. DaSilva, A. C. McConnell, J. S. Miller, Inorg. Chem. 54, 4629-4634 (2013). DOI: 10.1021/ic400250n

 

 Weak Ferromagnetic Ordering of the Li+[TCNE]•- (TCNE = Tetracyanoethylene) Organic Magnet with an Interpenetrating Diamondoid Structure,J.-H. Her,P. W. Stephens, R. A. Davidson, K. S. Min,J. D. Bagnato,K. van Schooten, C. BoehmeJ. S. Miller, J. Am. Chem. Soc. 135, 18060-18062 (2013).  DOI: 10.1021/ja410818e

 

Raman Evidence for Intradimer Bonding for the Multicenter, Long Bond in p-[TCNE]22- (TCNE = Tetracyanoethylene) Dimers, J. Casado, S. R. González, F. J. Ramírez, J. T. L. Navarrete, S. H. Lapidus, P. W. Stephens, H.-L. Vo, J. S. Miller, F. Mota, J. J. Novoa, Angew. Chem. Internat. Ed. 52, 6421–6425 (2013). Angew. Chem. 125, 6549-6553 (2013) DOI: 10.1002/anie.201207813 ACS Molecule of the week, July 15, 2013 http://www.acs.org/content/acs/en/molecule-of-the-week/archive/tetracyanoethylene.html

 

Keys for the existence of stable dimers of bis-TTF-functionalized molecular clips presenting short-distance [TTF]·+···[TTF]·+ interactions at room temperature, M. Fumanal, M. Capdevila-Cortada, J. S. Miller, J. J. Novoa, J. Am. Chem. Soc. 135, 13814–13826 (2013)). DOI: doi.org/10.1021/ja405352p

 

Thermodynamic Investigation by Heat Capacity Measurements of Ferrimagnetic A2Mn[Mn(CN)6] (A = K, Rb, Cs) Prussian Blue Compounds, Y. Kawamoto, S. Yamashita, R. Yoshimoto, Y. Nakazawa, J. G. DaSilva, C. M. Kareis, J. S. Miller, J. Phys.: Condens. Matter 26, 016001-1/6 (2013).  DOI: 10.1088/09538984/26/1/016001

 

Pressure-Dependent Increase in Tc and Magnetic Behavior of [Ru2(O2CBut)4]3[M(CN)6]•2H2O (M = Cr, Fe), J. G. DaSilva, J. S. Miller, Inorg. Chem. 52, 1418-1423 (2013).  DOI: 10.1021/ic302148s

 

Low Temperature Hysteretic Behavior of the Interpenetrating 3-D Network Structured [Ru2(O2CMe)4]3[Fe(CN)6] Magnet F. Haque, E. del Barco, R. S. Fishman, J. S. Miller, Polyhed. 64, 73-76 (2013). DOI: http://dx.doi.org/10.1016/j.poly.2013.02.049

 

First Row Transition Metal(II) Thiocyanate Complexes, and Formation of 1-, 2-, and 3-D Extended Network Structures of M(NCS)2(Solvent)2 (M = Cr, Mn, Co) Composition, E. Shurdha, C. Moore, A. L. Rheingold, S. H. Lapidus, P. W. Stephens, A. M. Arif,J. S. Miller, Inorg. Chem.52, 10583–10594 (2013).  DOI: org/10.1021/ic401558f

 

Dimer Structure of 1,2-Bipyridyldichloroiron(II), [FeIICl2bipy]2, and Chain Structure of 2,2'-Bipyridyldithiocyanato-iron(II), [FeII(NCS)2bipy]n. The Use of Powder X-Ray Diffraction Data To Determine the Structure of Werner Coordination Complexes, S. H. Lapidus, P. W. Stephens, E. Shurdha, J. G. DaSilva, J. S. Miller, Polyhed. 52, 713-718 (2013).  DOI: http://dx.doi.org/10.1016/j.poly.2012.07.081

 

Characterization of the Elusive Rhodizonate Ring Contraction C5O4(OH)CO2Me2- Intermediate to Croconate, F. Lu, A. L. Rheingold, J. S. Miller, Chem. Eur. J.19, 14795-14797 (2013).  DOI: 10.1002/chem.201303190

 

2012 Publications

 

N,N-7-Tricyanoquinomethanimine (TCQMI) as a cyano acceptor in the synthesis of new molecule-based magnetic systems, J. L. Arthur, C. E. Moore, A. L. Rheingold, S. H. Lapidus, P. W. Stephens, J. S. Miller, Adv. Functional Mater. 22, 1802-1811 (2012). DOI: 10.1002/adfm.201101937

 

Structures and Magnetostructural Correlation of Ferrimagnetic meso-Tetraphenylporphinatomanganese(III) dimethyl-N,N’-dicyanoquinonediiminide, [MnTPP]+[Me2DCNQI].-, J. L. Arthur, S. H. Lapidus, P. W. Stephens, J. S. Miller, Science China Chem. 55, 987-996 (2012).  DOI: 10.1007/s11426-012-4591-0

 

Thin Film Co[TCNE]2 and VyCo1-y[TCNE]2Magnetic Materials, P. K. Erickson, J. S. Miller, J. Mag. Magnet. Mater. 324, 2218-2223 (2012).  DOI:org/10.1016/j.jmmm.2012.02.037

 

Antiferromagnetic Ordering of MII(TCNE)[C4(CN)8]1/2 (M = Mn, Fe),A. C. McConnell, E. Shurdha, J. D. Bell, J. S. Miller, J. Phys. Chem. C116, 18952−18957 (2012). DOI: 10.1021/jp305523t.

 

A Mean Field Analysis of the Exchange Coupling (J) For 2- and 3-D Structured Tetracyanoethenide (TCNE•-)-based Magnets,A. C. McConnell, R. S. Fishman, J. S. Miller, J. Phys. Chem.C116, 16154-16160 (2012). DOI: org/10.1021/jp302765d

 

Pressure Induced Transition from an Antiferromagnet to a Ferrimagnet for MnII(TCNE)[C4(CN)8]1/2 (TCNE = Tetracyanoethylene),A. C. McConnell, J. D. Bell, J. S. Miller, Inorg. Chem. 51, 9978-9982 (2012). DOI: org/10.1021/ic3014865

 

Structure and Magnetic Ordering of the Anomalous Layered (2-D) Ferrimagnetic [NEt4]2MnII3(CN)8 and 3-D Antiferromagnetic Bridged-Layered [NEt4]MnII3(CN)7 Prussian Blue Analogs,C. M. Kareis J.-H. Her, P. W. Stephens, J. G. Moore, J. S. Miller, Chem. Eur. J. 18, 9281-9288 (2012). DOI: 10.1002/chem.201200672

 

Interpenetrating Three-Dimensional Diamondoid Lattices and Antiferromagnetic Ordering (Tc = 73 K) of Mn(CN)2,C. M. Kareis S. H. Lapidus, P. W. Stephens, J. S. Miller, Inorg. Chem. 51, 3046−3050 (2012). DOI: org/10.1021/ic202393d

 

Non-Prussian Blue Structures and Magnetic Ordering of Na2MnII[MnII(CN)6] and Na2MnII[MnII(CN)6]•2H2O, C. M. Kareis, S. H. Lapidus, J.-H. Her, P. W. Stephens, J. S. Miller, J. Am. Chem. Soc. 134, 2246-2254 (2012). DOI: 10.1021/ja209799y

 

A Mean Field Analysis of the Exchange Coupling (J) for Non-cubic Prussian Blue Analogue Magnets, J. G. DaSilva, A. C. McConnell, R. S. Fishman, J. S. Miller, J. Phys. Chem. C 116, 24752-24756 (2012) DOI: org/10.1021/jp309040h       

 

Neutron Diffraction Evidence for the Ferrimagnetic Ground State of a Molecule-based Magnet with Weakly Coupled Sublattices, R. S. Fishman, J. Campo, T. E. Vos, J. S. Miller, J. Phys.: Conden. Matter, 24, 496001 1/5 (2012).  DOI: 10.1088/0953-8984/24/49/496001

 

Magnetoelastic Coupling in the [Ru2(O2CMe)4]3[Cr(CN)6] Molecule-based Magnet in High Magnetic Field, T. V. Brinzari, P. Chen, L.-C. Tung, Y. Kim, D. Smirnov, J. Singleton, J. S. Miller, J. L. Musfeldt, Phys. Rev. B 85, 214411-1/7 (2012). DOI: 10.1103/PhysRevB.86.214411

 

Extended Network Thiocyanate- and Tetracyanoethanide- based First-Row Transition Metal Complexes,E. Shurdha, S. H. Lapidus, P. W. Stephens, C. E. Moore, A. L. Rheingold, J. S. Miller, Inorg. Chem.51, 9655–9665 (2012). DOI: org/10.1021/ic300804y

 

2011 Publications

 

Magnetically Ordered Molecule-based Materials, J. S. Miller, Chem. Soc. Rev.40, 3266-3296 (2011). DOI: 10.1039/c0cs00166j

 

Molecule-based Magnets, J. S. Miller, D. Gatteschi, Chem. Soc. Rev.40, 3065-3066 (2011). DOI: 10.1039/c1cs90019f.

 

Stabilization of Magnetic Ordering Observed for the Bridging NCN Group, J. L. Arthur, C. E. Moore, A. L. Rheingold, J. S. Miller, Inorg. Chem. 50, 2735-2737 (2011).  DOI: 10.1021/ic200083j

 

Structure and Magnetic Ordering of a 2-D Mn(TCNE)I(OH2) (TCNE = tetracyanoethylene) Organic-Based Magnet (Tc = 171 K), S. H. Lapidus, A. C. McConnell, P. W. Stephens, J. S. Miller, Chem. Comm.47, 7602-7604 (2011). DOI: 10.1039/c1cc10478k Front Cover  DOI: 10.1039/C1CC90091A

 

Unusual Long, Multicenter Cation···Anion Bonding Observed for Several Polymorphs of [TTF][TCNE], M. Capdevila-Cortada, J. J. Novoa, J. D. Bell, C. E. Moore, A. L. Rheingold, J. S. Miller, Chem. Eur. J.17, 9326-9341 (2011).  DOI: org/10.1002/chem.201100922.  Front Cover  DOI: 10.1002/chem.201190169

 

Determination of the Magnetic Ground State of a Polycrystalline Diruthenium Compound Obtained from Susceptibility Measurements R. S. Fishman, J. S. Miller, Phys. Rev. B 83, 0944331/5 (2011). DOI: 10.1103/PhysRevB.83.094433

 

Metamagnetic Phase Transition in a Diruthenium Compound with Interpenetrating Sublattices, R. S. Fishman, J. S. Miller, Polyhed. 30, 3131-3133 (2011).  DOI: 10.1016/j.poly.2011.03.009

 

Local Magnetism in the Molecule Based Metamagnet [Ru2(O2CMe)4]3[Cr(CN)6] Probed with Implanted Muons, T. Lancaster, F. L. Pratt, S. J. Blundell, A. J. Steele, P. J. Baker, J. D. Wright, R. S. Fishman, J. S. Miller, Phys. Rev. B 84, 092405-1/4 (2011).  DOI: 10.1103/PhysRevB.84.092405

 

Dinuclear CoII(NCMe)5CoII(NCS)4 Possessing Octahedral and Tetrahedral CoII Sites, E. Shurdha, C. E. Moore, A. L. Rheingold, J. S. Miller, Inorg. Chem.50, 10546–10548 (2011). DOI: 10.1021/ic201832d

 

2010 Publications

 

Zero-dimensional Organic-based Magnets Possessing Decamethylmetallocene, J. S. Miller, J. Mater. Chem. 20, 1846-1857 (2010).  DOI: 10.1039/b918080j  Front Cover J. Mater. Chem.20, 1823 (2010).  DOI: 10.1039/C002793B

 

Structure and Magnetostructural Correlation of Two Desolvated Polymorphs of Ferrimagnetic meso-Tetrakis(4-chlorophenyl)porphinatomanganese(III) Tetracyanoethenide, [MnTClPP]+[TCNE].-, J.-H. Her,P. W. Stephens, J. D. Bagnato, J. S. Miller, J. Phys. Chem. C 114, 20614-20620 (2010).  DOI: 10.1021/jp105109d

High field linear magnetoresistance in fully spin-polarized high-temperature organic-based ferrimagnetic semiconductor V(TCNE)x films, x ~ 2, N. P. Raju, V. N. Prigodin, K. I. Pokhodnya, J. S. Miller, A.J. Epstein, Synth Met.160, 307-310 (2010). DOI: 10.1016/j.synthmet.2009.09.025

 

Mn(TCNE)1.5(I3)0.5- a 3-D Network-Structured Organic-based Magnet and Comparison to a 2D Analog, K. H. Stone, P. W. Stephens, A. C. McConnell, E. Shurdha, K. I. Pokhodnya, J. S. Miller, Adv. Mater. 22, 2514-2519 (2010).  DOI: 10.1002/adma.200904238 Front Cover: DOI: 10.1002/adma.201090080

 

Average g-factors of Anisotropic Polycrystalline Samples, R. S. Fishman, J. S. Miller, J. Phys. Chem. C114, 11623-11626 (2010). DOI http://dx.doi.org/10.1016/j.poly.2013.02.012

 

Solid-State NMR Spectra and Long, Intradimer Bonding in the p-[TTF]22+ (TTF = Tetrathiafulvalene) DIcation, M. D. Halling, J. D. Bell, R. J. Pugmire, D. M. Grant, J. S. Miller, J. Phys. Chem. A 114, 6622-6629 (2010).  DOI: 10.1021/jp910509f

 

Anomalous Non-Prussian Blue Structure and Magnetic Ordering of K2MnII[MnII(CN)6] and Rb2MnII[MnII(CN)6],J.-H. Her, P. W. Stephens, C. M. Kareis, J. G. Moore, K. S. Min, J.-W. Park,G. Bali, B. S. Kennon, J. S. Miller, Inorg. Chem.49, 1524-1534 (2010). DOI: 10.1021/ic901903f  Front Cover: April 5, 2010, 49(#7) http://pubs.acs.org/action/showLargeCover?issue=347470232

 

Anomalous Stoichiometry, Layered Structure, and Magnetic Ordering of the Prussian Blue Analog [NEt4]2MnII3(CN)8,J.-H. Her, P. W. Stephens, C. M. Kareis, J. G. Moore, J. S. Miller, Angew. Chem. internat. Ed.49, 7773-7775 (2010); Angew. Chem. 122, 7939-7941 (2010). DOI: 10.1002/anie.201003381

 

Optical control of magnetization in a room-temperature magnet: V-Cr Prussian blue analog, K. D. Bozdag, J.-W. Yoo, N. P. Raju, A. C. McConnell, J. S. Miller, A. J. Epstein,Phys. Rev. B 094449-1/5 (2010). DOI: 10.1103/PhysRevB.82.094449

 

Layered (2-D) Structure of [Ru2(O2CMe)4]2[Ni(CN)4]Determined via Rietveld Refinement of Synchrotron Powder Diffraction Data,J.-H. Her, P. W. Stephens, B. S. Kennon, C. Liu, J. S. Miller, Inorg. Chim. Acta 364, 172-175 (2010).  DOI: 10.1016/j.ica.2010.07.059

 

Preparation and Structure of [RuII/III2(O2CMe)4]2[Fe(CN)5NO] and Magnetically Ordered Hx[RuII/III2(O2CMe)4]3-x-[Cr(CN)5NO] Possessing Interpenetrating Lattices, B. S. Kennon, K. H. Stone, P. W. Stephens, J. S. Miller, Inorg. Chim. Acta 363, 2137-2143 (2010). DOI: 10.1016/j.ica.2010.03.004

 

Observation of Magnetic Ordering for Layered (2-D) Potassium Diruthenium Tetracarbonate, K3[RuII/III2(O2CO)4]. A Rare Second Row Transition Metal-based Magnet, B. S. Kennon, J. S. Miller, Inorg. Chem.49, 5542-5545 (2010).  DOI: DOI: 10.1021/ic100357q

 

Pressure-Induced Phase Transition in a Molecule-Based Magnet with Interpenetrating Sublattices, R. S. Fishman, W. W. Shum, J. S. Miller, Phys. Rev. B 81, 172407-1-4 (2010).  DOI: 10.1103/PhysRevB.81.172407