Asymmetric Catalysis, Organometallic Chemistry & Organic Synthesis
Recent Research Highlights
Robinson, S. G.; Mack, J. B. C.; Alektiar, S. N.; Du Bois, J.; Sigman, M. S. Org. Lett.2020.
Ross, S. P.; Rahman, A. A.; Sigman, M. S. J. Am. Chem. Soc.2020.
Rosales, A. R.; Ross, S. P.; Helquist, P.; Norrby, P.-O.; Sigman, M. S.; Wiest, O. J. Am. Chem. Soc.2020.
Shrestha, A.; Hendriks, K. H.; Sigman, M. S.; Minteer, S. D.; Sanford, M. S. Chem. Eur. J.2020, 26, 5369.
Reid, J. P.; Hu, M.; Ito, S.; Huang, B.; Hong, C. M.; Xiang, H.; Sigman, M. S.; Toste, F. D. Chem. Sci.2020 https://doi.org/10.1039/D0SC00497A.
Miró, J.; Gensch, T.; Ellwart, M.; Han, S.-J.; Lin, H.-H.; Sigman, M. S.; Toste, F. D. J. Am. Chem. Soc.2020, 142, 6390.
Robinson, S. G.; Sigman, M. S. Acc. Chem. Res.2020, 53, 2, 289.
Bahamonde, A.; Al Rifaie, B.; Martín-Heras, V.; Allen, J. R.; Sigman, M. S. "Enantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines" J. Am. Chem. Soc.2019. doi.org/10.1021/jacs.9b03438
Kwon, Y.; Li, J.; Reid, J. P.; Crawford, J. M.; Jacob, R.; Sigman, M. S.; Toste, F. D.; Miller, S. J. "Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration" J. Am. Chem. Soc.2019, 141, 6698.
Crawford, J. M.; Sigman, M. S."Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?" Synthesis 2019, 51, 1021.
Hananya, N.; Reid, J. P.; Green, O.; Sigman, M. S.; Shabat, D. "Rapid chemiexcitation of phenoxy-dioxetane luminophores yields ultrasensitive chemiluminescence assays" Chem. Sci.2019, 10, 1380.
Hickey, D. P.; Sandford, C.; Rhodes, Z.; Gensch, T.; Fries, L. R.; Sigman, M. S.; Minteer, S. D. "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low Valent Co(I) Intermediates" J. Am. Chem. Soc.2019, 141, 1382.
Mack, J. B. C.; Walker, K. L.; Robinson, S. G.; Zare, R. N.; Sigman, M. S.; Waymouth, R. M.; Du Bois, J. "Mechanistic Study of Ruthenium-Catalyzed C−H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest" J. Am. Chem. Soc.2019, 141, 972.
Matthew S. Sigman
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Jolene Reid and Jen Crawford's JACS paper was highlighted in Synfacts
Congratulations to Nicholas Race for becoming the newest faculty member at Univerisy of Minnesota in the department of Chemistry!
Congratulations to Rachel Vaden for her new position at Pfizer as a research scientist in the cancer drug discovery group!
Congratulations to Elizabeth Bess for becoming the newest faculty member at UC-Irivine in Chemical Biology!
Yoonsu Park's work in collaboration with Zach Niemeyer from the Sigman lab was featured on the cover of Organometallics.
The Sigman group's work in collaboration with the Doyle group was highlighted as Synfact of the Month!
Nick Race's report in JACS was featured in Organic Chemistry Highlights .
The Sigman group's work on non-covalent interactions was discussed in Forbes.
Nick Race's report in JACS was highlighted in Synfacts.
Harsh Patel's report in JACS was highlighted in Synfacts.
Matthew Sigman is featured in C&E News for receiving the ACS award for creative work in synthetic organic chemistry.
Nick Race's report in JACS was highlighted in C&E News.
Celine Santiago’s report in JACS was highlighted in JACS Spotlights.
Anat Milo’s report in JACS was highlighted in JACS Spotlights.
David Hickey and David Schiedler's report in JACS was highlighted in JACS Spotlights.