Recent Research Highlights
B. P. Woods, M. Orlandi, C.-Y. Huang, M. S. Sigman, A. G. Doyle, J. Am. Chem. Soc. 2017 DOI: 10.1021/jacs.7b03448
F. D. Toste, M. S. Sigman, S. J. Miller"Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis" Acc. Chem. Res. 2017, 50, 609.
A. J. Neel, M. J. Hilton, M. S. Sigman, F. D. Toste "Exploiting non-covalent π interactions for catalyst design" Nature 2017, 543, 637.
Sevov, C. S.; Hickey, D. P.; Cook, M. E.; Robinson, S. G.; Barnett, S.; Minteer, S. D.*; Sigman, M. S.*; Sanford, M. S.* " Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applications,"J. Am. Chem. Soc. 2017, 139, 2924.
Zhang, C.; Tutkowski, B.; DeLuca, R. J.; Joyce, L. A. Wiest, O.; Sigman, M. S.* "Palladium-catalyzed enantioselective Heck alkenylation of trisubstituted allylic alkenols: a redox-relay strategy to construct vicinal stereocenters," Chem. Sci. 2017, 8, 2277.
Race, N. J.; Schwalm, C. S.; Nakamuro, T.; Sigman, M. S.* "Palladium-Catalyzed Enantioselective Intermolecular Coupling of Phenols and Allylic Alcohols," J. Am. Chem. Soc. 2016, 138, 15881.
Eiji, Y.; Hilton, M. J.; Orlandi, M.; Saini, V.; Toste, F.D.; Sigman, M. S.* "Development and Analysis of a Pd(0)-Catalyzed Enantioselective Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer," J. Am. Chem. Soc. 2016, 138, 15877.
Patel, H. H.; Sigman, M.S.* "Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols to Form Allylic Quaternary Centers,"J. Am. Chem. Soc. 2016,138, 14226.
Santiago, C. B.; Milo, A; Sigman, M. S.* "Developing a Modern Approach To Account for Steric Effects in Hammett-Type Correlations," J. Am. Chem. Soc. 2016, 138, 13424.
Chen, Z.-M.; Hilton, M. J.; Sigman, M. S.* "Palladium-Catalyzed Enantioselective Redox-Relay Heck Arylation of 1,1-Disubstituted Homoallylic Alcohols," J. Am. Chem. Soc. 2016, 138, 11461.
Niemeyer, Z.; Milo, A.; Hickey, D. P.; Sigman, M. S.* "Parameterization of phosphine ligands reveals mechanistic pathways and predicts reaction outcomes," Nature Chem. 2016, 8, 610–617.
