Recent Research Highlights
2020
Robinson, S. G.; Mack, J. B. C.; Alektiar, S. N.; Du Bois, J.; Sigman, M. S. Org. Lett.2020.
Ross, S. P.; Rahman, A. A.; Sigman, M. S. J. Am. Chem. Soc.2020.
Rosales, A. R.; Ross, S. P.; Helquist, P.; Norrby, P.-O.; Sigman, M. S.; Wiest, O. J. Am. Chem. Soc.2020.
Shrestha, A.; Hendriks, K. H.; Sigman, M. S.; Minteer, S. D.; Sanford, M. S. Chem. Eur. J.2020, 26, 5369.
Reid, J. P.; Hu, M.; Ito, S.; Huang, B.; Hong, C. M.; Xiang, H.; Sigman, M. S.; Toste, F. D. Chem. Sci.2020 https://doi.org/10.1039/D0SC00497A.
Miró, J.; Gensch, T.; Ellwart, M.; Han, S.-J.; Lin, H.-H.; Sigman, M. S.; Toste, F. D. J. Am. Chem. Soc.2020, 142, 6390.
Robinson, S. G.; Sigman, M. S. Acc. Chem. Res.2020, 53, 2, 289.
2019
Bahamonde, A.; Al Rifaie, B.; Martín-Heras, V.; Allen, J. R.; Sigman, M. S. "Enantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines" J. Am. Chem. Soc.2019. doi.org/10.1021/jacs.9b03438
Kwon, Y.; Li, J.; Reid, J. P.; Crawford, J. M.; Jacob, R.; Sigman, M. S.; Toste, F. D.; Miller, S. J. "Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration" J. Am. Chem. Soc.2019, 141, 6698.
Crawford, J. M.; Sigman, M. S."Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?" Synthesis 2019, 51, 1021.
Hananya, N.; Reid, J. P.; Green, O.; Sigman, M. S.; Shabat, D. "Rapid chemiexcitation of phenoxy-dioxetane luminophores yields ultrasensitive chemiluminescence assays" Chem. Sci.2019, 10, 1380.
Hickey, D. P.; Sandford, C.; Rhodes, Z.; Gensch, T.; Fries, L. R.; Sigman, M. S.; Minteer, S. D. "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low Valent Co(I) Intermediates" J. Am. Chem. Soc.2019, 141, 1382.
Mack, J. B. C.; Walker, K. L.; Robinson, S. G.; Zare, R. N.; Sigman, M. S.; Waymouth, R. M.; Du Bois, J. "Mechanistic Study of Ruthenium-Catalyzed C−H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest" J. Am. Chem. Soc.2019, 141, 972.
