Recent Research Highlights
Race, N. J.; Schwalm, C. S.; Nakamuro, T.; Sigman, M. S.* "Palladium-Catalyzed Enantioselective Intermolecular Coupling of Phenols and Allylic Alcohols," J. Am. Chem. Soc. ASAP. DOI: 10.1021/jacs.6b11486.
Eiji, Y.; Hilton, M. J.; Orlandi, M.; Saini, V.; Toste, F.D.; Sigman, M. S.* "Development and Analysis of a Pd(0)-Catalyzed Enantioselective Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer," J. Am. Chem. Soc. ASAP. DOI: 10.1021/jacs.6b11367.
Patel, H. H.; Sigman, M.S.* "Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols to Form Allylic Quaternary Centers," J. Am. Chem. Soc. 2016.DOI: 10.1021/jacs.6b09649
Santiago, C. B.; Milo, A; Sigman, M. S.* "Developing a Modern Approach To Account for Steric Effects in Hammett-Type Correlations," J. Am. Chem. Soc. 2016. DOI: 10.1021/jacs.6b08799.
Chen, Z.-M.; Hilton, M. J.; Sigman, M. S.* "Palladium-Catalyzed Enantioselective Redox-Relay Heck Arylation of 1,1-Disubstituted Homoallylic Alcohols," J. Am. Chem. Soc. 2016, 138, 11461.
Niemeyer, Z.; Milo, A.; Hickey, D. P.; Sigman, M. S.* "Parameterization of phosphine ligands reveals mechanistic pathways and predicts reaction outcomes," Nature Chem. 2016, 8, 610–617.